FADH2 reduces Î±.Î²-unsaturated thioesters to saturated thioesters. The reaction is thought to take place by a mechanism

Question:

FADH2 reduces Î±.Î²-unsaturated thioesters to saturated thioesters. The reaction is thought to take place by a mechanism that involves radicals. Propose a mechanism for this reaction.

Fantastic news! We've Found the answer you've been seeking!

Step by Step Answer:

Related Book For book-img-for-question

Organic Chemistry

ISBN: 978-0131407480

4th edition

Authors: Paula Yurkanis Bruice

See More Books

Question Posted: Jun 10, 2016 07:52 AM

See More Questions

Propose a mechanism for each reaction. (a) (b) (c) (d) OH H2SO heat OCH + CH3OH H20 CH2OH H2So4 heat CH OCH2CH CH CH,CH2OH (a minor product)
Propose a mechanism for the reduction of lipoate by FADH2.
A clever new method of peptide synthesis involves formation of an amide bond by reaction of an -keto acid with an N-alkyl hydroxylamine: The reaction is thought to occur by nucleophilic addition of...
Suppose you have a consumer that calls the lion() method within a Lion service. You have four distinct modules: consumer, service locator, service provider, and service provider interface. If you add...
Explain how channel members add value for manufacturers and consumers.
Whitegloves Janitorial Service was started 2 years ago by Jenna Olson. Because business has been exceptionally good, Jenna decided on July 1, 2020, to expand operations by acquiring an additional...
Researchers continue to find evidence that brains of adolescents behave quite differently than either brains of adults or brains of children. In particular, adolescents seem to hold on more strongly...
Assume a Gold Medal Sports outlet store began August 2012 with 44 pairs of running shoes that cost the store $33 each. The sale price of these shoes was $61. During August, the store completed these...
What role do institutions and governance systems play in fostering an environment conducive to empowerment, and how can these structures be reimagined to better serve marginalized populations ?
What is the solution of the recursive equation T (n) = 0.015625T +n?? (1/4) a) O(n') b) O(n' lg n) c) O(n* Ign) d) O(7*)
Nonenzyme-bound FAD is a stronger oxidizing agent than NAD+ How, then, can NAD+ oxidize the reduced flavoenzyme in the pyruvate dehydrogenase system?
A common way for FAD to become covalently bound to its enzyme is by having a proton removed from the C-8 methyl group and a proton donated to N-1. Then a cysteine or other nucleophilic side chain of...
On June 5, 2018, Brown, Inc., a calendar year taxpayer, receives cash of $750,000 from the county upon condemnation of its warehouse building (adjusted basis of $500,000 and fair market value of...
What is the structural basis underlying enzyme specificity, and how does it contribute to substrate recognition and binding?
If tane = 15 and cos=-, then what is sin e? Enter the answer as a fraction.
How do allosteric modulators exert their regulatory effects on enzyme activity, and what molecular mechanisms govern allosteric transitions?
Outstanding stock of the Wildhorse Corporation included 42800 shares of $5 par common stock and 10700 shares of 5%, $10 par non-cumulative preferred stock. In 2024, the company's board of directors...
Outback Outfitters sells recreational equipment. One of the company's products, a small camp stove, sells for $140 per unit. Variable expenses are $98 per stove, and fixed expenses associated with...
Problem require the use of a graphing calculator. For each problem, find f'(x) and approximate (to four decimal places) the value(s) of x where the graph of f has a horizontal tangent line. f(x) = x...
Sheldon and Leonard had a million-dollar idea. In order to make it happen, they have to do special research first. Only Kripke can help them in this matter. But Kripke is known to be the first-class...
Give a curved- arrow mechanism for the rearrangement shown in {in Eq. 10.12.)
Complete the following reactions. If no reaction is tikety, explain why. (a) (b) CH,SH + NaOH -_, (1 equiv.) 25 C CH OH
Outline a synthesis of each ether using either alcohol dehydration or alkene addition, as appropriate. (a) 2-methoxy-2-methylbutane (b) dibutyl ether
What is Data Flow Diagram? Explain the Steps ti draw data flow diagram?
What is the purpose of data flow diagrams? Do data flow diagrams show system logic and decision points? Explain.
Online Shopping of clothes. Please solve the following part: Logical Model Design .. 1.0 Data Flow Diagram.. 1.1 Context Diagram.. 1.2 Level 0 Data Flow Diagram.. 1.3 Level 1 Data Flow Diagram.. 1.4...

FADH2 reduces Î±.Î²-unsaturated thioesters to saturated thioesters. The reaction is thought to take place by a mechanism

Question:

. TAD RCHーCHCSR + FADH--→ RCH.CH-CSR + FAD

Step by Step Answer:

HC HC Doll soly NH H3C FADH RCHCHCSR ...View the full answer

Organic Chemistry

Students also viewed these Organic Chemistry questions