Question: Kharaschs earliest studies in this area were carried out in collaboration with graduate student Frank R. Mayo. Mayo performed over 400 experiments in which allyl

Kharasch’s earliest studies in this area were carried out in collaboration with graduate student Frank R. Mayo. Mayo performed over 400 experiments in which allyl bromide (3-bromo-1-propene) was treated with hydrogen bromide under a variety of conditions, and determined the distribution of the “normal” and “abnormal” products formed during the reaction. What two products were formed? Which is the product of addition in accordance with Markovnikov’s rule? Which one corresponds to addition opposite to the rule?

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