Long-range coupling between protons more than two carbon atoms apart is sometimes observed when ? bonds intervene.
Question:
Long-range coupling between protons more than two carbon atoms apart is sometimes observed when ? bonds intervene. An example is found in 1-methoxy-1-buten-3-yne. Not only does the acetylenic proton, Ha, couple with the vinylic proton Hb, it also couples with the vinylic proton HC, four carbon atoms away. The data are: Construct tree diagrams that account for the observed splitting patterns of ?Ha? Hb, and HC
Transcribed Image Text:
CH30 С-на Ha (3.08 8) H, (4.52 8) He (6.35 8) Jpc=7 Hz Ja-b = 3 Hz Ja-c = 1 Hz Ha-CEC-C Нь 1-Methoxy-1-buten-3-yne
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