Question: An NO molecule has thermally accessible electronically excited states. It also has an unpaired electron, and so may be expected to be paramagnetic. However, its
An NO molecule has thermally accessible electronically excited states. It also has an unpaired electron, and so may be expected to be paramagnetic. However, its ground state is not paramagnetic because the magnetic moment of the orbital motion of the unpaired electron almost exactly cancels the spin magnetic moment. The first excited state (at 121 cm-1) is paramagnetic because the orbital magnetic moment adds to, rather than cancels, the spin magnetic moment. The upper state has a magnetic moment of 21lB-1 because the upper state is thermally accessible the paramagnetic susceptibility of NO shows a pronounced temperature dependence even near room temperature. Calculate the molar paramagnetic susceptibility of NO and plot it as a function of temperature.
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