One of the most historically significant studies of chemical reaction rates was that by M. Bodenstein (z.
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One of the most historically significant studies of chemical reaction rates was that by M. Bodenstein (z. physik. Chem. 29,295 (1899)) of the gas-phase reaction 2 Hl(g) -t H2(g) + I2(g) and its reverse, with rate constants k and k', respectively. The measured rate constants as a function of temperature are
Demonstrate that these data are consistent with the collision theory of bimolecular gas-phase reactions.
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T/K 647 666 683 700 716 781 k/(22.4 dm³ mol ¹ min¹) 0.230 0.588 1.37 3.10 6.70 105.9 K/(22.4 dm³ mol-¹ min¹) 0.0140 0.0379 0.0659 0.172 0.375 3.58
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Linear regression analysis of Inrate constant against 1T yields the following results In k224 dm mol ...View the full answer
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