For the styrene production process given in Project B.3 in Appendix B, do the following: 1. Construct

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For the styrene production process given in Project B.3 in Appendix B, do the following:

1. Construct a process conditions matrix (PCM) for the process, and determine all conditions of special concern.

2. Explain the reasons for using the conditions of special concern in the reactor.

3. Suggest any process alternatives for Part (b). The process flow diagram is shown in Figure B.3.1. Ethylbenzene feed is mixed with recycled ethylbenzene,R-401 R-402 E-403 E-404 E-405 V-401 C-401 Styrene Styrene Product Product Product Three- Reactor Reactor

C6H5C2H5 ethylbenzene 1 C6H5 C2 H3 + H styrene 3 hydrogen (B.3.1) C6H5 C2H5 C6H6 + CH4 benzene ethylene

The styrene product can spontaneously polymerize at higher temperatures. Because product styrene is sentTable B.3.1 Stream Tables for Unit 400 Stream Number Temperature 136.0 (C) Pressure (kPa) Vapor mole fraction

Component Flowrates (kmol/h) Water Ethylbenzene 121.00 Styrene Hydrogen Benzene Toluene Ethylene Methane 0.00

Temperature 722.0 (C) Pressure (kPa) Vapor mole fraction Total flow (kg/h) 170.0 1.00 566.6 160.0 1.00 Total

Water Ethylbenzene 0.00 Styrene Hydrogen Benzene Toluene Ethylene Methane Stream Number Temperature (C)

Vapor mole fraction Total flow (kg/h) Water 1.00 Total flow (kmol/h) Component Flowrates (kmol/h) Styrene

Benzene Toluene Ethylene Methane Stream Number Pressure (kPa) Vapor mole fraction 1.37 1.86 Total flow (kg/h)

Total flow (kmol/h) Component Flowrates (kmol/h) Water Ethylbenzene Styrene Hydrogen Benzene Toluene Ethylene

Temperature 123.8 (C) Pressure (kPa) Vapor mole fraction Total flow (kg/h) Total flow (kmol/h) Water 200.0

Benzene Toluene Ethylene Methane 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.16 0.65 0.00 0.00 0.00

Stream Number Temperature (C) Pressure (kPa) Vapor mole fraction Total flow (kg/h) 26 70.0 200.00 0.00 289.5

Component Flowrates (kmol/h) Water Ethylbenzene Styrene Hydrogen Benzene Toluene Ethylene Methane 0.00 0.10

Table B.3.3 Major Equipment Summary for Unit 400 Compressors and Drives C-401 Carbon steel W = 134 KW 60%

1 shell--2 tube passes Q=13,530 MJ/h E-402 1 shell--2 tube passes Q = 12,951 MJ/h E-407

316 stainless steel A = 226 m Boiling in shell, process fluid in tubes 1 shell--2 tube passes Q = 8322 MJ/h

1 shell--2 tube passes Q = 44,595 MJ/h E-404 Carbon steel A = 702 m Boiling in shell, process fluid in tubes

cw in shell, process fluid in tubes 1 shell--2 tube passes Q = 136,609 MJ/h Fired Heater H-401 Fired

80% efficient P-402 A/B Centrifugal/electric drive Carbon steel 80% efficient P-405 A/B Centrifugal/electric

W = 1.33 kW (actual) 80% efficient P-403 A/B Centrifugal/electric drive Carbon steel W = 0.574 kW (actual)

Reactors R-401 316 stainless steel, packed bed Cylindrical catalyst pellet (diameter = 1.6 mm, length =3.2

54% efficient Feed on tray 31 12-in tray spacing 1-in weirs Column height = 61 ft = 18.6 m Vessels V-401

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Related Book For  answer-question

Analysis Synthesis And Design Of Chemical Processes

ISBN: 9780134177403

5th Edition

Authors: Richard Turton, Joseph Shaeiwitz, Debangsu Bhattacharyya, Wallace Whiting

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