Derive the analogues of the Gibbs-Duhem equations (Eqs. 8.2-8 and 8.2-9) for the constraints of a.Constant temperature
Question:
Derive the analogues of the Gibbs-Duhem equations (Eqs. 8.2-8 and 8.2-9) for the constraints of
a.Constant temperature and volume
b. Constant internal energy and volume
c. Constant entropy and volume
Transcribed Image Text:
-N от P,Ni C v (OP) ₁ dP+ ► N; d0; = 0 T,Ni i=1 dT - N N 20 ( ) ат - (р) dT ӘT P,Ni T,Ni C dP+Ex; d0; = 0 i=1 (8.2-8a) (8.2-8b)
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Related Book For
Chemical Biochemical And Engineering Thermodynamics
ISBN: 9780470504796
5th Edition
Authors: Stanley I. Sandler
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