The Boyle temperature is defined as the temperature at which the second virial coefficient B is equal
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The Boyle temperature is defined as the temperature at which the second virial coefficient B is equal to zero. a. Recognizing that any equation of state can be expanded in virial form, find the Boyle temperature for the Redlich-Kwong equation of state in terms of the parameters in that equation.
b. The Redlich-Kwong parameters for carbon dioxide are a = 6.466×10−4 m6 MPa K0.5 mol−2 and b = 2.971 × 10−3 m3 mol−1. Estimate the Boyle temperature for carbon dioxide, assuming that it obeys the Redlich-Kwong equation of state.
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Chemical Biochemical And Engineering Thermodynamics
ISBN: 9780470504796
5th Edition
Authors: Stanley I. Sandler
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