The sublimation pressure of carbon dioxide as a function of temperature is and the molar volume of

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The sublimation pressure of carbon dioxide as a function of temperature is 

T (K) P (kPa) 130 0.032 155 1.674 185 44.02 194.5 205 101.3 227

and the molar volume of CO2 is 2.8 × 10−5 m3/mol. 

a. Determine the heat of sublimation of CO2 at 190 K. 

b. Estimate the fugacity of solid CO2 at 190 K and 200 bar.

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