(a) Describe the changes in bonding that would occur in benzene if two electrons were removed from...

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(a) Describe the changes in bonding that would occur in benzene if two electrons were removed from the HOMO (highest occupied molecular orbital). This removal would correspond to an oxidation of benzene to C6H62+.

(b) Describe the changes in bonding that would occur if two electrons were added to the LUMO (lowest unoccupied molecular orbital). This addition would correspond to a reduction of benzene by adding two electrons to give C6H62–. Do you expect these ions to be diamagnetic or paramagnetic?

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Chemical Principles The Quest For Insight

ISBN: 9781464183959

7th Edition

Authors: Peter Atkins, Loretta Jones, Leroy Laverman

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