Consider the following galvanic cell: A 15.0-mol sample of (mathrm{NH}_{3}) is added to the Ag compartment (assume

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Consider the following galvanic cell:

Ag- 1.00 M Ag+ -Cd 1.00 M Cd2+

A 15.0-mol sample of $\mathrm{NH}_{3}$ is added to the Ag compartment (assume 1.00 L of total solution after the addition). The silver ion reacts with ammonia to form complex ions as shown:

$\mathrm{Ag}^{+}(a q)+\mathrm{NH}_{3}(a q) ightleftharpoons \mathrm{AgNH}_{3}{ }^{+}(a q)$

\[K_{1}=2.1 \times 10^{3}\]

AgNH3+ (aq) + NH3(aq) Ag(NH3)2(aq) K = 8.2 x 10

Calculate the cell potential after the addition of $15.0 \mathrm{~mol}$ $\mathrm{NH}_{3}$.

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Chemical Principles

ISBN: 9780618946907

6th Edition

Authors: Steven S Zumdahl

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Question Posted: Jan 25, 2024 05:01 AM

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Consider the following galvanic cell: A 15.0-mol sample of (mathrm{NH}_{3}) is added to the Ag compartment (assume

Question:

Ag- 1.00 M Ag+ -Cd 1.00 M Cd2+

Step by Step Answer:

To calculate the cell potential after the addition of ammonia NH3 to the silver Ag compartment of the galvanic cell we need to consider the effects of the complex ion formation reactions on the concen...View the full answer

Chemical Principles

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