You can imagine Rydbergs excitement, just after he had identified his formula and found that it worked

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You can imagine Rydberg’s excitement, just after he had identified his formula and found that it worked for all the known lines in the spectrum of atomic hydrogen. Calculate the wavelength of the radiation emitted by a hydrogen atom for n1 = 2 and n2 = 3. Identify the spectral line in Fig. 1A.10b.

ANTICIPATE  Because n1 = 2 the wavelength should match one of the lines in the Balmer series.

PLAN The frequency is given by Eq. 2. Convert frequency into wavelength by using Eq. 1.wavelength X X frequency = speed of light C (1)={}} 2 y = n = 1,2, ..., Mg = n + 1, n + 2,... (2)

Fig. 1A.10b954.6 Balmer series 656.3 486.1 434.0 410.2 (b) Infrared Visible Wavelength, 2m 121.6 Lyman series 102.6 -

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Chemical Principles The Quest For Insight

ISBN: 9781464183959

7th Edition

Authors: Peter Atkins, Loretta Jones, Leroy Laverman

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