The color and wavelength of the absorption maximum for [Ni(H 2 O) 6 ] 2+ , [Ni(NH

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The color and wavelength of the absorption maximum for [Ni(H2O)6]2+, [Ni(NH3)6]2+, and [Ni(en)3]2+ are given in Figure 23.30. The absorption maximum for the [Ni(bipy)3]2+ ion occurs at about 520 nm.

11 11 11 A IL 1L 12 1 1 1 [Ni(H,O0),F+ Max absorption in visible = 720 nm [Ni(en),+ [Ni(NH,),P* Max absorption in visible = 570 nm Max absorption in visible = 545 nm Energy


(a) What color would you expect for the [Ni(bipy)3]2+ ion?

(b) Based on these data, where would you put bipy in the spectrochemical series?

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Chemistry The Central Science

ISBN: 9780321910417

13th Edition

Authors: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus

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