Calculate the potential of a platinum electrode immersed in a solution that is (a) 0.0513 M in

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Calculate the potential of a platinum electrode immersed in a solution that is
(a) 0.0513 M in K4Fe(CN)6 and 0.00589 M in K3Fe(CN)6.
(b) 0.0300 M in FeSO4 and 0.00825 M in Fe2(SO4)3.
(c) Buffered to a pH of 4.85 and saturated with H2 at 1.00 atm.
(d) 0.1455 M in V(OH)4 +, 0.0802 M in VO2+, and 0.0800 M in HClO4.
(e) Prepared by mixing 50.00 mL of 0.0507 M Ce(SO4)2 with an equal volume of 0.100 M FeCl2 (assume solutions were 1.00 M in H2SO4, and use formal potentials).
(f) Prepared by mixing 25.00 mL of 0.0832 M V2(SO4)3 with 50.00 mL of 0.00628 M V(OH)4 + and has a pH of 1.00.
(g) Draw a schematic diagram for each of the half-cells described in (a) through (f).

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Fundamentals Of Analytical Chemistry

ISBN: 9780357450390

10th Edition

Authors: Douglas A. Skoog, Donald M. West, F. James Holler, Stanley R. Crouch

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