In Example 13-12, we used the vant Hoff equation to determine the temperature at which for the

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In Example 13-12, we used the van’t Hoff equation to determine the temperature at which for the reaction 2 SO2(g) + O2(g) ⇌ 2 SO3(g). Obtain another estimate of this temperature with data from Appendix D and equations (13.13) and (13.17). Compare your result with that obtained in Example 13-12.

Example 13-12

Use data from Table 13.8 and Figure 13-10 to estimate the temperature at which K = 1.0 x 106 for the reaction

2 SO(g) + O(g) = 2 SO3(g)

Table 13.8

TABLE 13.8 Equilibrium Constants, K, for the Reaction 2 SO(g) + O(g) 2 SO3(g) at Several Temperatures T, K

Figure 13-10

In K 8.0- 6.0- 4.0 - 2.0- 0.0 - -2.0- -4.0 T 8.0 Slope 1 9.0 3.4 x 10-4K-1 7.6 - 3.4 x 10-4K-1 2.2  104 K 1

Eq. 13.13

AG =   S (13.13)

Eq. 13.17

A,G-RT In K = (13.17)

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General Chemistry Principles And Modern Applications

ISBN: 9780132931281

11th Edition

Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette

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