(a) In each of the following complexes, determine the overall charge, n, which may be positive or...
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(a) In each of the following complexes, determine the overall charge, n, which may be positive or negative: [FeII(bpy)3]n, [CrIII(ox)3]n, [CrIIIF6]n, [NiII(en)3]n, [MnII(ox)2(OH2)2]n, [ZnII(py)4]n, [CoIIICl2(en)2]n.
(b) If the bonding in [MnO4]− were 100% ionic, what would be the charges on the Mn and O atoms? Is this model realistic? By applying Pauling’s electroneutrality principle, redistribute the charge in [MnO4]− so that Mn has a resultant charge of +1. What are the charges on each O atom? What does this charge distribution tell you about the degree of covalent character in the Mn–O bonds?
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a To determine the overall charge n of each complex we need to consider the oxidation states of the metal and the ligands involved The oxidation state of the metal is represented by the Roman numeral ...View the full answer
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