(a) Which of the following octahedral complexes are chiral: cis-[CoCl 2 (en) 2 ] + , [Cr(ox)...
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(a) Which of the following octahedral complexes are chiral: cis-[CoCl2(en)2]+, [Cr(ox)3]3−, trans-[PtCl2(en)2]2+, [Ni(phen)3]2+, [RuBr4(phen)]−, cis-[RuCl(py)(phen)2]+?
(b) The solution 31P NMR spectrum of a mixture of isomers of the square planar complex [Pd(SCN)2(Ph2PCH2PPh2)] shows one broad signal at 298 K. At 228 K, two singlets and two doublets (J = 82 Hz) are observed and the relative integrals of these signals are solvent dependent. Draw the structures of the possible isomers of [Pd(SCN)2(Ph2PCH2PPh2)] and rationalize the NMR spectroscopic data.
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a Chirality of octahedral complexes Chirality in octahedral complexes arises when there is no internal plane of symmetry in the complex meaning the complex cannot be superimposed on its mirror image F...View the full answer
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