(a) Rationalize why each of the following is diamagnetic: [Os(CN) 6 ] 4 , [PtCl 4 ]...
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(a) Rationalize why each of the following is diamagnetic: [Os(CN)6]4−, [PtCl4]2−, OsO4 and trans-[OsO2F4]2−.
(b) Solution 77Se and 13C NMR spectra for the octahedral anions in the compounds [Bu4N]3[Rh(SeCN)6] and [Bu4N]3[trans-Rh(CN)2(SeCN)4] are tabulated below. Assign the spectra and explain the origin of the observed coupling patterns. [Additional data: see Table 4.3]
Table 4.3.
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a Rationalization of Diamagnetism Diamagnetism is a property exhibited by substances that have no unpaired electrons and are not attracted to a magnet...View the full answer
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