Apart from direct O-atom transfer (Fig. 26.50), another mechanism proposed for Mo enzymes is indirect O-atom transfer,
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Apart from direct O-atom transfer (Fig. 26.50), another mechanism proposed for Mo enzymes is indirect O-atom transfer, also known as coupled electron-proton transfer. In this mechanism, shown in Fig. 26.69 for sulfite oxidase, the O atom that is transferred originates instead from an uncoordinated H2O molecule. Propose a way to distinguish between direct and indirect O-atom transfer mechanisms.
Figure 26.69.
Figure 26.50.
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To distinguish between direct and indirect Oatom transfer mechanisms the following experimental approaches can be considered Isotope labeling Incorpor...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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