The reaction of TeCl 4 with PPh 3 in THF solution in air leads to the formation
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The reaction of TeCl4 with PPh3 in THF solution in air leads to the formation of the salt (Ph3PO)2H]2[Te2Cl10]. Structural data reveal that each Te centre in the anion is in an approximately octahedral environment.
(a) Suggest a structure for [Te2Cl10]2−.
(b) The cation [(Ph3PO)2H]+ is derived from the phosphine oxide Ph3PO. Suggest a structure for the cation and comment on its bonding.
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a Structure of Te2Cl102 Based on the information provided that each Te center in the anion is in an ...View the full answer
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