The reaction of [ZrCl 4 (dppe)] with Mg(CH 3 ) 2 gives [Zr(CH 3 ) 4 (dppe)].
Question:
The reaction of [ZrCl4(dppe)] with Mg(CH3)2 gives [Zr(CH3)4(dppe)]. NMR spectra indicate that all methyl groups are equivalent. Draw octahedral and trigonal prism structures for the complex and show how the conclusion from NMR supports the trigonal prism assignment (P.M. Morse and G.S. Girolami, J. Am. Chem. Soc., 1989, 111, 4114).
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To understand why the NMR spectra support the trigonal prism assignment for the complex ZrCH34dppe lets first draw the structures of the octahedral an...View the full answer
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Related Book For 
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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