According to Perrys Handbook, the system water + isobutanol forms an atmospheric pressure azeotrope at 67.14 mol%

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According to Perry’s Handbook, the system water + isobutanol forms an atmospheric pressure azeotrope at 67.14 mol% water and 89.92°C. Based on these data, we can estimate the van Laar coefficients to be A12 = 1.566; A21 = 3.833 at 273 K. Estimate the liquid-liquid mutual solubilities of each component in each liquid phase at 273 K.

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