Acrolein (C 3 H 4 O) + water exhibits an atmospheric (1 bar) azeotrope at 97.4 wt%

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Acrolein (C3H4O) + water exhibits an atmospheric (1 bar) azeotrope at 97.4 wt% acrolein and 52.4°C. For acrolein: Tc = 506 K; Pc =51.6 bar; and ω = 0.330; MW =56.

(a) Determine the value of kij for the Peng-Robinson equation that matches this bubble pressure at the same liquid composition and temperature.

(b) Tabulate P, y at 326.55 K and x = {0.57, 0.9, 0.95, 0.974} via the Peng-Robinson equation using the kij determined above.

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