The enthalpy of reaction for many biological reactions and surfactants is strongly temperature- dependent, but instead of

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The enthalpy of reaction for many biological reactions and surfactants is strongly temperature- dependent, but instead of using full heat capacities, the temperature dependence can be characterized by differences in heat capacities ΔCP = CP,prod – CP,react, typically assumed to be independent of temperature.

(a) The heat of reaction is represented by ΔH = ΔHR + ΔCP(T – TR). Show thatT AGR (77) + ACp[(T-TR) - Tln (77)]- [T-TR T R T R AHR TR AGT= AGR

(b) Provide an equation consistent with part (a) for the temperature dependence of the entropy of reaction.

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