Question: In Practice Problem 7.7, you should have predicted that, based solely on London forces, PH3 (18 electrons) has a higher boiling point than NH 3

In Practice Problem 7.7, you should have predicted that, based solely on London forces, PH3 (18 electrons) has a higher boiling point than NH3 (10 electrons). In fact, this is not the case. Explain why.


Data from Problem 7.7

Draw a dot diagram for NH3 and one for PH3.

Is either molecule polar? (The electronegativities of N, P, and H are 3.0, 2.1, and 2.1, respectively.)

In which substance are the London forces stronger? Explain.

Basing your answer solely on the London forces in the two substances, which substance would you expect to have the higher boiling point? Explain.

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