The BouguerBeer law (sometimes called the LambertBeer law or Beers law) states that A = alc, where

Question:

The Bouguer–Beer law (sometimes called the Lambert–Beer law or Beer’s law) states that A = alc, where A is the of a solution, defined as log10 (I0/I ), where I0 is the incident intensity of light at the appropriate wavelength and I is the transmitted intensity; l is the length of the cell through which the light passes; and c is the concentration of the absorbing substance. The coefficient a is called the molar absorptivity if the concentration is measured in moles per liter. The following is a set of data for the absorbance of a set of solutions of disodium fumarate at a wavelength of 250 nm.

A 0.1425 0.2865 0.4280 0.5725 0.7160 0.8575 c(mol I-) 100 2.00 3.00 4.00 5.00 6.00 x10-4 x10-4 x10-4 x10-4 x10-4 x10-4

Using a linear least-squares fit with intercept set equal to zero, find the value of the absorptivity a if l = 1.000 cm. For comparison, carry out the fit without specifying zero intercept.

Fantastic news! We've Found the answer you've been seeking!

Step by Step Answer:

Related Book For  book-img-for-question
Question Posted: