The Dieterici equation of state is Pe a/Vm RT (V m b) = RT, where P
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The Dieterici equation of state is
Pea/Vm RT (Vm − b) = RT,
where P is the pressure, T is the temperature, Vm is the molar volume, and R is the ideal gas constant. The constant parameters a and b have different values for different gases. For carbon dioxide, a = 0.468 Pa m6 mol−2, b = 4.63 × 10−5 m3 mol−1. Without linearization, find the molar volume of carbon dioxide if T = 298.15 K and P = 10.000 atm = 1.01325 × 106 Pa. Use Mathematica, Excel, or trial and error.
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