Question: The correlation function for vibrational relaxation QQ(t) can be written in second quantized form, using dimensionless normal coordinates where [a, a + ] = 1.
The correlation function for vibrational relaxation 〈QQ(t)〉 can be written in second quantized form, using dimensionless normal coordinates
where [a, a+] = 1. (a) Show that the Heisenberg representations of the operators a and a+ are

Q=(a + a)/2,
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Part a The Heisenberg representation of an operator A is given by At expiHt A expiHt where H is the ... View full answer
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