Question: Use the partition functions in Equations 1.98, 1.99, and 1.100 to find the translational, rotational, and vibrational contributions to the average energy of a diatomic

Use the partition functions in Equations 1.98, 1.99, and 1.100 to find the translational, rotational, and vibrational contributions to the average energy of a diatomic molecule. Compare each result to the prediction of the equipartition theorem, which states that in the classical limit each degree of freedom contributes 12(1/2)kBT to the average energy.


Equations 1.98


Equations 1.99


Equations 1.100

Ztr 2mkT h 73/2 V

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