Consider the -D-pyranose forms of glucose and talose (Fig. 24.3). Suggest one reason why talose contains a

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Consider the β-D-pyranose forms of glucose and talose (Fig. 24.3). Suggest one reason why talose contains a smaller fraction of β-pyranose form than glucose.

- - H  CH=0 -OH HO OH  OH -OH CHOH H  CH-O H H -OH HO -OH - CHOH H H CH O  - -H HO OH H -OH  CHOH CH=0 H -H H

D-(+)-allose - -  D-(+)-altrose CH=O  OH OH CHOH D-(-)-ribose  H D-(+)-glucose D-(+)-mannose D-(-)-gulose

D-(-)-erythrose H CH=0 -OH CHOH D-(+)-glyceraldehyde D-(-)-threose FIGURE 24.3 The D family of aldoses. Each

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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