In 1985, two researchers at the University of California, Riverside, carried out the reaction given in Fig.
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In 1985, two researchers at the University of California, Riverside, carried out the reaction given in Fig. P28.51.
The equilibrium mixture contained compound A (22%), a single stereoisomer of B (47%), and a single stereoisomer of C (31%). Predict the stereochemistry of compounds B and C at the carbon marked with the asterisk (*). Explain your prediction.
Transcribed Image Text:
CH₂ C3H17 DH A CH3 Figure P28.51 OH 'H 98 °C (dark) CH₂ C8H17 D CH3 H B * OH "H t CH₂ C8H17 H CH3 D C * OH H
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This is a 17 sigmatropic rearrangement which according to ...View the full answer
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