The boiling points of tert-butyl alcohol (2-methyl-2-propanol) and 1-butanol differ by 36C (82 and 118). Before proceeding,

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The boiling points of tert-butyl alcohol (2-methyl-2-propanol) and 1-butanol differ by 36°C (82° and 118°). Before proceeding, draw their structures.

(a) Which has the higher boiling point? Give a reason for this difference.

(b) How would the differences in their structures affect the ΔS_s (entropy of solution) contribution to their water solubilities?

(c) One compound is miscible with water and the other has a limited solubility of 8 mass percent. Which compound is miscible? Explain.

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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Question Posted: Nov 29, 2023 08:03 AM

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The boiling points of tert-butyl alcohol (2-methyl-2-propanol) and 1-butanol differ by 36C (82 and 118). Before proceeding,

Question:

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a Even though they have the same molecular weight 1butanol has a higher boiling p...View the full answer

Organic Chemistry

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