Use the principles of Sec. 1.3B to predict the geometry of BF 3 . What hybridization of
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Use the principles of Sec. 1.3B to predict the geometry of BF3. What hybridization of boron is suggested by this geometry? Draw an orbital diagram for hybridized boron similar to that for the carbons in ethylene shown in Fig. 4.3, and provide a hybrid orbital description of the bonding in BF3.
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ENERGY 2p ↑ 2s ↑ 2px 2py ↑ 1s 2Pz atomic carbon: (1s)²(2s)²(2px) (2py) unaffected by hybridization mix 2s, 2px, and 2p, orbitals unaffected by hybridization 2pz 2(sp²) ↑ 1s # carbon in ethylene FIGURE 4.3 Orbitals of an sp²-hybridized carbon are derived conceptually by mixing one 2s orbital and hybrid two 2p orbitals, in this case orbitals the 2px and 2p, orbitals, shown in red. Three sp² hybrid orbitals are formed (red) and one 2p, orbital remains unhybridized (blue).
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Boron trifluoride trifluoroborane BF 3 is trigonal planar with FBF bond angles of 120 Because hybrid...View the full answer
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