At sufficiently high temperatures, the van der Waals equation has the form P L RT>(V m -

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At sufficiently high temperatures, the van der Waals equation has the form P ‰ˆ L RT>(Vm- b). Note that the attractive part of the potential has no influence in this expression. Justify this behavior using the potential energy diagram of Figure 1.10.

Figure 1.10

Ideal gas Real gas Itrarlsition (1)A

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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