Because U is a state function, (/V (U/T) V ) T = (/T (U/V) T ) V

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Because U is a state function, (∂/∂V (∂U/∂T)V)T = (∂/∂T (∂U/∂V)T)V . Using this relationship, show that (∂CV/∂V)T = 0 for an ideal gas.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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