Chlorine monoxide (ClO i ) demonstrates three bimolecular self-reactions: The following table provides the Arrhenius parameters for

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Chlorine monoxide (ClO i ) demonstrates three bimolecular self-reactions:

Ron: C10 • (g) + C10 • (g)->C1,(g) + O,(g) Rxn,: C10 • (g) + C10 • (g)->C1.• (g) + C100 • (g) Rxn; : C10 •

The following table provides the Arrhenius parameters for this reaction:

4 (M-'s-1) E.(kJ/mol) Rxm 6.08 x 108 3×1 13.2 Rxn, 179 x 1010 20.4 Rxn3 2.11 × 10° 11.4

a. For which reaction is ΔH€¡ greatest and by how much relative to the next closest reaction?

b. For which reaction is ΔS€¡ the smallest and by how much relative to the next closest reaction?

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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