Formaldehyde is produced commercially by the catalytic oxidation of methanol. In a side reaction, methanol is oxidized

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Formaldehyde is produced commercially by the catalytic oxidation of methanol. In a side reaction, methanol is oxidized to CO2.

CH3OH + 02 → CH2O + H2O CH3OH + 02 CO, + 2H2O →


A mixture containing 55.6 mole% methanol and the balance oxygen enters a reactor at 350°C and 1 atm at a rate of 4:60 × 104 L/s. The reaction products emerge at the same temperature and pressure at a rate of 6:26 × 104 L/s. An analysis of the products yields a molar composition of 36.7% CH2O, 4.1% CO2, 14.3% O2, and 44.9% H2O. The required reactor cooling rate is calculated to be 1:05 × 105 kW.

(a) Is the calculated cooling rate correct for the given stream data?

(b) The stream data cannot be correct. Prove it.

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Elementary Principles of Chemical Processes

ISBN: 978-1119498759

4th edition

Authors: Richard M. Felder, ‎ Ronald W. Rousseau, ‎ Lisa G. Bullard

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