From the results of Exercise 17.5a, calculate the rotational contribution to the molar entropy of gaseous water
Question:
From the results of Exercise 17.5a, calculate the rotational contribution to the molar entropy of gaseous water at 25°C.
Data in Exercise 17.5a,
Calculate the rotational partition function of H2O at 298 K from its rotational constants 27.878 cm−1, 14.509 cm−1, and 9.287 cm−1. Above what temperature is the high-temperature approximation valid to within 10 per cent of the true value?
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Solution Let the rotational constant be given by R 27878 109 c...View the full answer
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