Rearrange the van der Waals equation of state, p=nRT/(V nb) n 2 a/V 2 ,
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Rearrange the van der Waals equation of state, p=nRT/(V – nb) – n2a/V2, to give an expression for T as a function of p and V (with n constant). Calculate (∂T/∂p)V and confirm that (∂T/∂p)V =1/(∂p/∂T)V . Go on to confirm Euler’s chain relation (Mathematical background 2).
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Related Book For
Physical Chemistry Thermodynamics And Kinetics
ISBN: 9781464124518
10th Edition
Authors: Peter Atkins, Julio De Paula
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