The molar heat capacity C P,m of SO 2 (g) is described by the following equation over

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The molar heat capacity CP,mof SO2(g) is described by the following equation over the range 300 K < T < 1700 K:

Сри 3.093 + 6.967 x103÷- 45.81x10-7 -2 +1.035 ×10 K- 9. K K

In this equation, T is the absolute temperature in kelvin. The ratios T€/K€ ensure that CP,m has the correct dimension. Assuming ideal gas behavior, calculate q, w, ΔU, and ΔH if 1.50 moles of SO2(g) is heated from 22.5°C to 1140.°C at a constant pressure of 1 bar. Explain the sign of w.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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