Two empirical equations of state of a real gas are as follows: Evaluate (S/V) T for each

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Two empirical equations of state of a real gas are as follows:

Evaluate (∂S/∂V)_T for each gas. For an isothermal expansion, for which kind of gas (also consider a perfect gas) will ΔS be greatest? Explain your conclusion.

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Physical Chemistry Thermodynamics And Kinetics

ISBN: 9781464124518

10th Edition

Authors: Peter Atkins, Julio De Paula

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Question Posted: Oct 14, 2022 07:58 AM

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Two empirical equations of state of a real gas are as follows: Evaluate (S/V) T for each

Question:

RT a van der Waals: p=V-b V m m RTe-a/RTVm Dieterici: p= V-b

Step by Step Answer:

For the van der Waals gas we have SV pVT pTV SV RTVmbVm2bVm aRTVm2bVm SV ...View the full answer

Physical Chemistry Thermodynamics And Kinetics

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