Question: 1 , = kb = 1.3806 x 10-23 J/K; B ; 9(B) = ; 9; exp[;f] ; khT L(a;, Ej, a,b) = InW + a

1 , = kb = 1.3806 x 10-23 J/K; B ; 9(B) = ; 9; exp[;f] ; khT L(a;, Ej, a,b) = InW + a (Ek ak A) B(Ek akEk E); A = Ek ak; E = Ekakek Energy (cm-1) Number of states = 5 EO E1 E2 0.000000 158.265 226.977 3 1 1. The 3 lowest lying atomic energy levels of an oxygen atom are listed above a. Use complete sentences to describe how to calculate the probability to be in Ey at 1000K, considering only the energies above. b. Perform the calculation described in part a. a ap 2. (E) is equal to In[q(B)] a. Derive (E) = ; E;P; using the above relationship. b. Using results from part a and question 1, what is the average energy of an oxygen molecule at 1000K? 3. Use Lagrange multipliers to show that the values of a, through an that maximize In(W) satisfy, a; = exp(-a) exp(-BE;) = 1 , = kb = 1.3806 x 10-23 J/K; B ; 9(B) = ; 9; exp[;f] ; khT L(a;, Ej, a,b) = InW + a (Ek ak A) B(Ek akEk E); A = Ek ak; E = Ekakek Energy (cm-1) Number of states = 5 EO E1 E2 0.000000 158.265 226.977 3 1 1. The 3 lowest lying atomic energy levels of an oxygen atom are listed above a. Use complete sentences to describe how to calculate the probability to be in Ey at 1000K, considering only the energies above. b. Perform the calculation described in part a. a ap 2. (E) is equal to In[q(B)] a. Derive (E) = ; E;P; using the above relationship. b. Using results from part a and question 1, what is the average energy of an oxygen molecule at 1000K? 3. Use Lagrange multipliers to show that the values of a, through an that maximize In(W) satisfy, a; = exp(-a) exp(-BE;) =
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