$2.$ Identify the appropriate control volume for quantifying the following pollutant concentrations:

a$.$ Heavy metal contamination of soil resulting from a municipal solid waste landfill.

b$.$ Coliform bacteria concentrations in a river downstream of a lake that is fed by both snowmelt and agricultural runoff.

c$.$ Volatile organic compounds in the air inside a home downwind of a chemical tank fire.

d$.$ Microplastics in a detention pond that receives stormwater runoff from a grocery store parking lot.