Question: 5. a) The 0 - 0 transition for an allowed electronic transition in a diatomic molecule is 35,000 cm-! The vibrational frequency of the excited

5. a) The 0 - 0 transition for an allowed electronic transition in a diatomic molecule is 35,000 cm-! The vibrational frequency of the excited state is 400 cm and the ground state vibrational frequency is 525 cmWhich absorption transition has the highest intensity, if the states have the potential energy curves and vibrational wavefunctions shown in the figure? (The arrows are merely there to help you visualize the process, not necessarily the energy levels involved.) Explain your answer. (5 pts) E Energy E Nuclear Coordinates b) What is this absorption in cm-!? (4 pts) c) Which fluorescence transition has the highest intensity? (4 pts) d) What is this fluorescence peak, in cm-I? (4 pts)
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