Question: (5) As we learned in our class, anharmonic oscillator represents diatomic molecules better than the 1D-HO. According to this model, frequency (in cm1) of IR

 (5) As we learned in our class, anharmonic oscillator represents diatomic

(5) As we learned in our class, anharmonic oscillator represents diatomic molecules better than the 1D-HO. According to this model, frequency (in cm1) of IR radiation required to cause fundamental (01) and 1ti overtone (02) transitions can be estimated using: v~obs=v~02v~ex~e(vi+1)forfundamentalmodev~obs=2v~04v~ex~e(2vi+3)for1stovertone Here, v~0 is the fundamental vibrational frequency predicted by 1D-HO model, v~ex~e is the 1st anharmonicity constant which represents the deviation from 1D-HO model, and vi represents the initial vibrational quantum number. If 01 and 02 bands for 1H35Cl are observed, respectively, at 2885.98cm1,5667.98cm1, calculate v~0 and v~ex~e

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