Question: Chapter 9 : Kinetics and mechanisms : solvent exchange 9 . 1 What mechanisms do the following activation parameters for solvent exchange suggest? The rate

Chapter 9 : Kinetics and mechanisms : solvent exchange
9.1 What mechanisms do the following activation parameters for solvent exchange
suggest?
The rate constant for acetonitrile exchange at [Ru(MeCN)6]2+ is more than 108
times slower than that for water exchange at [Ru(H2O)6]2+. The rate constant for
water exchange at [Fe(H2O)6]2+ is more than 108 times faster than that for water
exchange at [Ru(H2O)6]2+. To what factors may these very large differences be
attributed?
 Chapter 9 : Kinetics and mechanisms : solvent exchange 9.1 What

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