Question: Circle what's wrong with the problem and write out corrections rate law for the reversible storage of energy by the NQ couple. P3-168 What five

Circle what's wrong with the problem and write out corrections
Circle what's wrong with the problem and write out corrections rate law

rate law for the reversible storage of energy by the NQ couple. P3-168 What five things are wrong with this solution? The reaction 2A +BC follows an elementary law. At 50C the specific reaction rate constant is 10(m?/mol)-/s with an activation energy of 400J/mol. What is the rate of reac- tion at 100C when the concentrations of A and B are 2 and 4 moles/m respectively? Solution In order to completely consume a 4 molar solution of B would require an 8 molar concentration of A. Because the initial concentration of A is only 2 molar, A is the limiting reactant. Thus we choose A as our basis of calculation and divide by its stoichiometic coefficient of A, to get A+ because the reaction follows an elementary rate law -r = kc CB2 Converting the rate constant at 50C to k at 100C ( K(100C) = (50C)exp(KG, 7) 100] 4005 1 10exp 1.98 50 100 = 75.4(m /mol)/s Substituting for k, CA and CB -TA = (75.4)(2)(4)/2 = 301 mol 3 m.h

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