Question: Consider a system that undergoes a phase change from phase a to phase b at equilibrium temperature T and equilibrium pressure p . At these
Consider a system that undergoes a phase change from phase a to phase b at equilibrium temperature T
and equilibrium pressure p
. At these equilibrium conditions, the heat absorbed per mole of material undergoing this transition is q
, and there is a molar volume change of
V
,m. The molar heat capacities for the
and
phases are Cp,m,
and Cp,m,
; they are independent of temperature.
A.) Write a thermodynamic cycle that would allow you to calculate the equilibrium transition temperature corresponding to a pressure of 1000 bar. Use the cycle to write an equation that could in principle be solved to calculate T
at 1000 bar.
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