Question: Ethane ( C 2 H 6 ) is chlorinated in a continuous reactor: C 2 H 6 + C l 2 C 2 H 5

Ethane (C2H6) is chlorinated in a continuous reactor: C2H6+Cl2C2H5Cl+HCl
Some of ethane is converted in an undesired side reaction: C2H6+2Cl2C2H4Cl2+2HCl
Flow rate of the feed to the reactor (not the fresh feed to process) is 150molh, containing 4
moles of ethane (C2H6) per mole of chlorine (Cl2). The conversion of C2H6 in the reactor is 15%
and for every 100 moles of ethane consumed in the reactor, 80 moles of monochloroethane
(C2H5Cl) exit in reactor products.
A separation process is used to separate the products: ethane and chlorine are recycled to the
reactor and monochloroethane (C2H5Cl) leaves the system to be sold as a product, and HCl and
C2H4Cl2 are discarded.
Compulsory questions (a-d))
a) Draw and label the flow chart of the process
b) Calculate the molar flow rate (molh) of C2H6 leaving the reactor
c) Calculate the molar flow rate (molh of C2H5Cl leaving the reactor
d) Calculate the molar flow rate (molh) of C2H6 and Cl2 in the fresh feed
Optional questions (e-h)
e) What is the OVERALL conversion of C2H6? Explain why the overall conversion is higher than
the single pass conversion.
f) Calculate the molar flow rate (molh) of the stream containing HCl and C2H4Cl2
g) Calculate the overall yield of the desired product C2H5Cl
h) Calculate the overall selectivity of the desired product C2H5Cl with respect to the undesired
product C2H4Cl2
 Ethane (C2H6) is chlorinated in a continuous reactor: C2H6+Cl2C2H5Cl+HCl Some of

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