Question: For the hydrogen atom and the trial function e-where a is a variational parameter, using atomic units, calculate the expectation values of the potential energy

 For the hydrogen atom and the trial function e-where a is
a variational parameter, using atomic units, calculate the expectation values of the

For the hydrogen atom and the trial function e-where a is a variational parameter, using atomic units, calculate the expectation values of the potential energy (the operator is - ) and the kinetic energy (the operator is 2r dr "ar ) as functions of a. Add these to get the energy as a function of a, find the value of a for which the energy is minimum, and calculate the energy for this value of a. (In your integrals, don't forget to include the r factor from the from the spherical coordinates volume element.) dr : 1/2 2 -ar 1 dr 2 a -ar 1 re dr= (TL ; 1/2 4 a a O' 1 dr= 2a -ar 3 74 . 1/2 8a

Step by Step Solution

There are 3 Steps involved in it

1 Expert Approved Answer
Step: 1 Unlock blur-text-image
Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock
Step: 3 Unlock

Students Have Also Explored These Related Physics Questions!